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Solar Heating and Cooling Needs New Materials

Aventa has earmarked 2011 as the year in which polymeric solar thermal breaks into the mainstream market.

Andrew Lee, Contributor
February 25, 2011  |  11 Comments

If renewable energy was a family, solar thermal technology might unkindly be seen as a dependable but rather unfashionable cousin whose life hasn't seen much excitement for some years.

Solar thermal systems have undeniably benefitted from continual incremental improvements, but not much about the most commonly used flat-plate collector seems to fundamentally alter. A module containing a black, glass-covered metal absorber plate harvests solar radiation. This is backed by tubing (generally made of copper or aluminium), through which water or other heat exchange fluid is pumped into a building's space heating or hot water system.

According to those developing a new breed of collectors, however, the use of materials such as copper bring significant downsides that could be eliminated by replacing them with a new generation of advanced, high-performance polymers.

An International Energy Agency (IEA) Solar Heating & Cooling (SHC) Programme task force group has spent the last four years plotting a plastic revolution in solar thermal.

The international research group involved in SHC Task 39 highlighted a wide range of potential benefits if the copper and other metals used in components such as the absorber plate and tubing could be removed. These benefits include the need for fewer separate materials and therefore manufacturing processes, lower weight and freedom from the sharp price fluctuations associated with copper in particular.

Polymer components could be manufactured more cheaply and flexibly thanks to the well-established process of extrusion, which could easily produce the exact dimensions needed to integrate collectors with buildings of all shapes and sizes.

Components would be lighter to transport and easier to install, and could possibly even come in a variety of attractive hues to do away with the 'any colour as long as it is black' approach of conventional collectors.

For all the virtues of their proposed plastic systems, however, the Task 39 group was faced with the fact that metals are used in solar thermal collectors for a very good reason. The extremes and fluctuations of UV radiation and temperature that a solar thermal system must withstand would prove too much for most polymers, especially over a required service life that spans at least 20 or more years.

 An Aventa solar thermal development in Oslo (Source: Dahle & Breitenstein)

The key temperature for a polymer operating in solar thermal is around the 160°C mark. This is the maximum that a system would have to cope with under stagnation conditions (the point at which the thermal process produces the highest operating temperatures), even though the base temperature requirements for domestic space heating and hot water are significantly lower.

Alongside detailed technical investigation, the IEA group's work was broadly split into two main areas designed to overcome these limitations.

One looked at using cheaper, readily available commodity plastics and adding some sort of overheating protection 'failsafe' mechanism to prevent them being exposed to temperatures they cannot deal with.

A second strand of investigation concentrated on the development of more sophisticated high-performance polymers with the properties needed to withstand the demands of solar thermal systems. Norwegian company Aventa, a participant in Task 39, is a notable pioneer in this area and says it is close to bringing a commercial polymer-based system to market.

Founded as a corporate entity in 2005 – but building on work underway since the early 1990s at the University of Oslo's physics department – Aventa has earmarked 2011 as the year in which polymeric solar thermal breaks into the mainstream market.

Aventa has collaborated with US group Chevron Phillips Chemical to develop a high-performance polyphenylene sulphide (PPS) polymer able to cope with the 160oC stagnation level temeperature and remain stable and reliable for the lifetime of a commercial system.

The Norwegian company's all-polymer collector, based on Chevron Phillips' Xtel PPS alloy, is currently in the final stages of testing and performance certification. Accordingly, Aventa says it plans to begin volume production this year.

John Rekstad, the company's chairman and a professor of physics at Oslo, says the crucial virtue of the material is its ability to operate effectively in a thermal environment, unaided by overheating protection, while also offering all the manufacturing flexibility that comes with the extrusion process.

'Of course Teflon, for example, can sustain temperatures of 340°C. The problem with Teflon is you can't extrude it or make products out of it in the way we need to,' says Rekstad.

According to Rekstad, the need to establish the Aventa polymer's ability to operate effectively over the lengthy service periods needed for solar thermal systems is one reason that the path to commercialisation has been a relatively slow one. The company has worked its way through the process of acquiring the necessary certification needed to enter the market and carried out the tests required to 'satisfy ourselves that we can stick to our promises,' says Rekstad. 'That takes time, but it is absolutely necessary to gain acceptance in the market.'

With those hurdles almost overcome, Aventa hopes to expand production capacity to 40,000 m² of collector surface this year and has developed a new extrusion die in conjunction with its manufacturing partners, which will make the polymer components on its behalf.

The end result is a system that can more than hold its own in terms of performance and cost, claims Rekstad. 'The base cost for production per unit can be reduced to a level of almost half per unit of conventional collectors,' he says.

In terms of overall system efficiency – the measure that Aventa prefers to use – Rekstad says the company's device is equivalent to conventional collectors. The absorber plate, for example, is made of extruded twin wall sheets. Even though its thermal conductivity is inferior to copper's, Aventa says the improved efficiency of its heat transfer process results in a performance that is equally robust.

In the Aventa system even the glass collector cover is replaced by a 10 mm sheet of UV-protected polycarbonate, removing the problems associated with glazing large surface areas.

Of course, the ultimate test of polymers in solar thermal applications will be acceptance by their end-consumers. These are ultimately homeowners and commercial building operators but, more urgently, the construction and building design industries. 'This is very important to create the shortest possible path from production to installation,' says Rekstad.

A sign of the construction industry's interest came in late 2010 when OBOS, Norway's largest building co-operative, took a 23% stake in Aventa, becoming its largest shareholder. 'They want to use our system in a number of projects, because they see it as a way of combining solar with the processes they are used to in building and construction,' says Rekstad. 'They can integrate these elements into buildings more easily than is the case with conventional collectors,'.

OBOS will run its own trials by building two identical houses, one with an Aventa solar thermal system and the second with an air-water heat pump. The two buildings will then be monitored to discover which delivers the best energy efficiency and cost performance.

At the time of its share acquisition, OBOS said it saw no reason why Aventa should not go on to become a leading player in the European solar thermal industry. For that to happen it will have to help kick-start a market that, by the admission of many in the industry, is struggling to make sufficient progress at the moment and like a number of other renewable energy sectors actually contracted in Europe last year.

Rekstad claims that for too long solar thermal technology has remained in the shadow of the PV sector, which has enjoyed the lion's share of government promotion, taxpayer subsidies and publicity. 'Market figures tell a story of impressive worldwide expansion, but this just has not got the same attention as PV, for example,' says Rekstad. He continues: 'Yet total energy production for solar thermal is eight or nine times bigger than the total output of energy from all electricity-producing solar technologies installed worldwide.'

Rekstad believes part of the reason is the lack of interest in solar thermal among major power utilities, a situation that he claims is easily explained: 'The energy companies' reason for existing is to sell energy. Solar thermal is all about needing to use less energy.'

Rekstad has been evangelical about the benefits of solar thermal heating for far longer than polymers have been part of the picture. He built Norway's first solar thermal house in 1977 in what he admits some saw as 'a crazy experiment' and has monitored the results ever since.

'I've lived in the house for 34 years and in that time we've had to pay €120 to replace the pump. That has been the only cost and in that time we have saved an average of 7.5 MWh annually. I'm not considered that crazy anymore.'

11 Comments

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E Fried
E Fried
June 15, 2012
Is there an update or are selective polymeric absorbers dead on arrival? The last news is from 2010. http://aventa.frifugl.net/eng/News/Press-releases/AVENTA-launches-a-high-performance-polymer-solar-collector
Dave Wilson
Dave Wilson
March 3, 2011
In the fall of 1980 I began graduate school in Chemical Engineering at MIT. I had done some work in solar energy and was thrilled to be in the same department as the by-then Emeritus Hoyt C. Hottel, who was, from the 1950s through the 1970s, THE world authority on solar thermal engineering. His textbook, Radiative Heat Transfer, was the standard of excellence in the field.

That first week I made way to his office, threw myself at his feet and begged him to tell me the secrets of solar energy.

He looked at me with a scowl and urged me not to waste my time with it! As I looked at him in shock he went on to explain that after decades of research he had concluded that solar thermal hot water systems would never be cost effective because there was no escaping the fact that they could not be well made without glass and copper, and that these two materials would always have their price closely tracking the price of the considerable fossil fuel energy that went into their manufacture.

Here we are, over thirty years later, and his words ring true as ever. During this time we've seen real revolutions in PV and wind generation, but I see fewer rooftop thermal panels today than in 1980. Now, for the umpteenth time we are excited that THIS time there will be low cost materials that will do the job cost effectively.

As hopeful as I am, I'm not holding my breath. Sorry.
Patrick O'Leary
Patrick O'Leary
March 1, 2011
Bundling benefits makes systems more attractive. Futura Solar has done this with its 'Sawtooth Solar Daylighter' for low profile commercial/industrial buildings (US patent 6,912,816 & PCT pending).

This system revives 'sawtooth' roofing with additional solar benefits. In addition to a daylighting roof, we add a 2 pass air heater for process air. The air heater feeds from just below the ceiling, providing incidental space conditioning & heat recovery. The absorber plate can be painted black, amorphous PV or SWH.

Most of the energy that falls on the roof can then be directed to whatever process takes place in the business below the roof, with little in the way of transmission loss.

Compare that to a PPA. Even with Gallium Arsenide doped crystalline PV at 20%, wiring into a flourescent bulb at 12-15& yields a total energy conversion efficiency of 2-3%. Daylighting provides 2/3's to 3/4's of direct sunlight, without the solar loading. The solar loading is captured in the air heater and provides process hot air.

Consider a commercial laundry: light on the factory floor, hot air for the driers and hot water for the washers. This will turn a low margin, high energy cost business into a higher margin, lower energy cost business.
Thomas M
Thomas M
March 1, 2011
Not all plumbers prefer the new plastic tubing. Plastic tubing systems have come and gone over the years. Only time testing will prove their safety and reliability.
Add UV exposure damage, thermal cycling, chemical reaction with varying circulating fluids, impact, repair-ability, toxic bonding agents etc. to the testing also.
Copper has already stood the test of time.
Ben Stinson
Ben Stinson
March 1, 2011
This is an excellent advancement in the solar thermal industry. Not only are plastics cheaper and easier to handle but do not have the same corrosion issues associated with them when installing in marine and extreme marine environments. It is unlikely they will be able to be used for solar cooling but for SDHW it is step in the right direction.
ANONYMOUS
March 1, 2011
Polymer tubing is already the preferred way to plumb hot and cold water in new construction so there should be a choice of materials that don't leach. On the other hand, heat pumps are cheap so alternatives such as brine might be used.

Cold climate is not an issue for solar thermal. One of the more interesting solar thermal projects I've seen is north of 60. Thermal collectors are combined with solar panels and serve dual functions to take away excess energy as heat which improves the net energy efficiency of the system and to defrost the system in the morning (fluid is drained at night then pumped back into the panels in the morning to defrost the glass and liberate snow load).

The main difference between copper pipe and plastic pipe at low temperature is that the copper will burst if the water becomes frozen. The main issue with polymers at low temperature is their glass transition temperature below which they become brittle. One has to be careful to protect them from impact.
Support Team Education Group
Support Team Education Group
March 1, 2011
Education on the performance of solar thermal is critical. Please see the links below to follow LIVE solar hot water system telemetry online 24/7.

We provide a lot of support to anyone researching this requirement.

http://www.surfacepower.com/blog/

http://www.surfacepower.com/live.html

Regards, SP Edu Team, support@surfacepower.com
Roy Depape
Roy Depape
March 1, 2011
It sounds like general acceptance about these polymers may take some time to achieve, but I do believe Aventa is heading in the right direction here.
William Fitch
William Fitch
February 26, 2011
Hi:

The types of systems used depends on where you are. In the NE, evac tubes and pressurized inside preheat tanks are the best choice. In general, ICS type units do not fly in freezing climates, no matter what they are made of.
I think as the market moves more and more towards evacs, again in colder climates, the two product types will continue to differentiate themselves.
It probably will be a long time before non metal solutions can satisfy the evac design engineering requirements.....
That said, it would be great to have a glass and ceramic based evac tube with almost zero mass, low specific heat and high thermal conductivity.

.....Bill
Anumakonda Jagadeesh
Anumakonda Jagadeesh
February 26, 2011
Though Solar Water heating is the simplest Solar application(Solar Thermal),the present designs are not popular because they necessitate pressurised water(Through overhead tank). In Apartments it is difficult to get space.

I designed a vertical and cylindrical solar water heater with stainless steel drums of capacity 100 litres. There is an Omni- directional Stainless steel polished reflector to increase the temperature in the lower drum. The upper drum(Auxialary) is meant to supply cold water to the bottom drum when hot water is drawn from bottom drum. There is a tap to take out hot water from the top of the bottom drum(as hot water rises due to natural convection). The drums are painted mat black to get absorption and covered with thick transparent Polyethylene sheet to create greenhouse effect. 100 litres system costs about US$150 and hot water + 20 degrees Celsius ambient temperature can be obtained. A temperature drum of half a degree Celsius per hour has been observed during overnight storage. Stainless steel material is chosen because this solar water heater can be used as a preheated water device for cooking. One can use preheated water to cook food by any cooking device, electric, gas,even firewood.

Another factor is social and cultural factors apart from technical that forbid wider usage of Solar Thermal systems in the Sunbelt countries. In Japan there are estimated 6 million Solar Water heaters. Japanese have the habit of taking bath in the evening and as such any little increase in temperature is enough where as in many developing countries people take bath in the morning as such there has to be effective storage of hot water overnight for taking bath in the morning. TECHNOLOGY IS CULTURE SPECIFIC.

Dr.A.Jagadeesh Nellore(AP),India
Thomas M
Thomas M
February 25, 2011
Just be careful when choosing polymers for drinking/residential water situations. Properly time and heat test for caustic leaching.
But as alway, there are situations where plastic piping is good for solar. Pool heating, low temp heating, preheating, solar showers etc...

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Andrew Lee

Andrew Lee

Andrew Lee is a freelance contributor to the Renewable Energy World network of publications. He is the former chief editor for Renewable Energy World magazine and conference director for Renewable Energy World Europe and Renewable Energy...
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