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Ocean Thermal Energy Conversion and CO2 Sequestration

Christopher D. Barry, P.E.
July 01, 2008  |  21 Comments

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I haven't heard much about Ocean Energy lately. It would seem to me that on a global scale the ocean would have a lot to offer us for energy development, perhaps with additional benefits while we're at it. Are there any new developments on that front? -- Jason S., Key West, Florida

Ocean Thermal Energy Conversion (OTEC) extracts solar energy through a heat engine operating across the temperature difference between warm surface water and cold deep water. In the tropics, surface waters are above 80°F, but at ocean depths of about 1,000 meters, water temperatures are just above freezing everywhere in the ocean. This provides a 45 to 50°F temperature differential that can be used to extract energy from the surface waters.

Of course, with such a low differential, the Carnot efficiencies of such a scheme are very low; for a system operating between 85°F and 35°F the maximum theoretical efficiency is only 9.2% and real efficiencies will be less. Regardless, OTEC has been demonstrated as a technically feasible method of generating energy.

There are a number of different concepts for the heat engine including low temperature difference Stirling cycle engines and direct use of water vapor derived from the surface waters that is condensed with the cold water, but most concepts have a Rankine cycle using a fluid with a low boiling point.

It works like this: Warm water is used to heat a fluid such as ammonia to vapor. The vapor then runs through a turbine to generate power and the cold water is used to condense it. Let's use ammonia as an example. Ammonia boils at 85°F and 166 psi and condenses at 35°F and 66 psi. This gives us 100 psi to run a turbine. Unfortunately this cycle only provides about 7% efficiency, though it can be boosted a bit by superheating, reheating and similar strategies used in steam cycles. However the big advantage is that OTEC is a solar power system with no collector — the ocean itself is the collector. This means it also is available constantly.

Considerations, Problems and Solutions

There are many practical issues as well. Again, with ammonia as the example, ammonia attacks copper bearing alloys, but only copper alloys resist marine fouling, and only a small amount of fouling is enough to drastically cut efficiency. Systems using ammonia have to have sophisticated waterside cleaning systems. There are also issues with the design of efficient low head turbines, very high performance heat exchangers, the long cold water pipe, and the platform, if it is floating (most OTEC designs are floating platforms, "grazing" in the open ocean).

Finally, there is the problem of using the energy. Most OTEC plants will be far at sea, because deep water in the tropics is generally far from energy markets, so the energy is "stranded."

Since the 70's a few developers have been experimenting with approaches using different fluids, with improved heat exchanger and turbine technology and innovative platform and cold water pipe designs and materials.

Other developers have been working on techniques to use the stranded energy, usually by making an energy intensive chemical at sea that can be used as a fuel or to supplant energy that would otherwise be used to make the chemical. One candidate is ammonia, which currently requires substantial energy to provide the world's need for fertilizers, and can be used as an alternative fuel as well. Another is sodium, made from salt; combining eleven pounds of sodium with water makes one pound of hydrogen. So sodium is potentially a very effective "storage medium" for hydrogen. These developments, plus the growing cost of energy, have people looking again at OTEC.

OTEC and Carbon Sequestering

However, deep cold water is laden with nutrients. In the tropics, the warm surface waters are lighter than the cold water and act as a cap to keep the nutrients in the deeps. This is why there is much less life in the tropical ocean than in coastal waters or near the poles. The tropical ocean is only fertile where there is an upwelling of cold water.

One such upwelling is off the coast of Peru, where the Peru (or Humboldt) Current brings up nutrient laden waters. In this area, with lots of solar energy and nutrients, ocean fertility is about 1800 grams of carbon uptake per square meter per year, compared to only 100 grams typically. This creates a rich fishery, but most of the carbon eventually sinks to the deeps in the form of waste products and dead microorganisms.

This process is nothing new; worldwide marine microorganisms currently sequester about forty billion metric tonnes of carbon per year. They are the major long term sink for carbon dioxide.

In a recent issue of Nature, Lovelock and Rapley suggested using wave-powered pumps to bring up water from the deeps to sequester carbon. But OTEC also brings up prodigious amounts of deep water and can do the same thing. In one design, a thousand cubic meters of water per second are required to produce 70 MW of net output power.

We can make estimates of fertility enhancement and sequestration, but a guess is that an OTEC plant designed to optimize nutrification might produce 10,000 metric tonnes of carbon dioxide sequestration per year per MW. The recent challenge by billionaire Sir Richard Branson is to sequester one billion tonnes of carbon dioxide per year in order to halt global warming, so an aggressive OTEC program, hundreds of several hundred MW plants might meet this.

In economic terms, optimistic guesses at OTEC plant costs are in the range of a million dollars per MW. Since a kilowatt-hour (kWh) of electricity generated by coal produces about a kilogram of carbon dioxide, a carbon tax of one to two cents per kWh might cover the capital costs of an OTEC plant in carbon credits alone. The equivalent in gasoline tax would be ten to twenty cents per gallon. With gasoline above three dollars per gallon and electricity above ten cents per kilowatt, these are not entirely unreasonable charges.

More Testing Is Necessary

The actual effectiveness of OTEC in raising ocean fertility and thereby sequestering carbon still has to be verified, and there has to be a careful examination of other possible harmful environmental impacts — an old saying among engineers is "it seemed like a good idea at the time."

The most important issue is that the deep water already has substantial dissolved carbon dioxide, and so an OTEC plant may actually release more carbon than it sequesters, or it might just speed up the existing cycle, sending down as much as it brings up with no net effect. This question has to be answered before OTEC is implemented.

It may also be possible to optimize sequestration by being selective about the depths that water is drawn from, or possibly by adding other trace nutrients, especially those that enhance species that sequester carbon in shells.

An OTEC plant optimized for ocean fertility will also probably be different than one optimized to generate power, so any OTEC-based carbon scheme has to include transfer payments of some sort — it won't come for free. Finally, who owns the ocean thermal resource? Most plants will be in international waters, though these waters tend to be off the coasts of the developing world.

Saving the World

There might be an additional benefit: Another saying is "we aren't trying to solve world hunger," but we may have. Increased ocean fertility may enhance fisheries substantially. In addition, by using OTEC energy to make nitrogen fertilizers, we can improve agriculture in the developing world. OTEC fertilizer could be sold to developing countries at a subsidy in exchange for using the tropic oceans.

If we can solve the challenges of OTEC, especially carbon sequestration, it would seem that the Branson Challenge is met, and we have saved the earth, plus solving world hunger. Since President Jimmy Carter originally started OTEC research in the '70's, he deserves the credit. I'm sure he will find a good use for Sir Richard's check.

Christopher D. Barry is a naval architect and co-chair of the Society of Naval Architects and Marine Engineers ad hoc panel on ocean renewable energy. He has worked in design agencies, shipyards and manufacturers in the marine industry and in offshore oil exploration and currently works for the Coast Guard, but is not associated with any OTEC program. The opinions expressed are those of the author and do not necessarily reflect the opinions or policy of SNAME or of the Coast Guard.

21 Comments

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Robert Cohen
Robert Cohen
April 21, 2009
Following is my latest position statement on the possibility of using ocean thermal power plants and plantships for deep-sea sequestration of CO2. In the absence of needed R&D by experts, this is the best non-conjectural statement I can make right now about this possibility:

Assuming that there is some viable means of sequestering CO2 in the deep ocean, and that some candidate technology can perform this task cost-effectively, it would seem that ocean thermal plants and plantships will be well-positioned to consider adding this incremental task to their existing functions.
Robert Cohen
Robert Cohen
April 21, 2009
Please note that somehow my Comments 11 and 12 above became reversed in sequence. Comment 12 was posted first, and then, for lack of space, I posted Comment 11. [Ideally, I wish the editors of this Web site would combine Comment 11 with Comment 12, omitting the words "If I am permitted to add some concluding sentences to what I just posted, they are as follows:"]
Ted Jagusztyn
Ted Jagusztyn
December 20, 2008
Thank you Christopher Barry for bringing OTEC back to the forefront. I am an inventor - entrepreneur from Fort Lauderdale, Florida. I have two patent pending inventions focused on bringing OTEC into the mainstream. It is a hybrid district energy land based plant.
It's called SolAirOTEC.
The innovations include:
1) Using horizontal directional drilling tp drill protected seawater conduits. "PSC" .This eliminates the costly and precarious process of laying pipes in the ocean. Moreover, the investment is protected from hurricanes.
2) Use Wind Turbines to produce compressed air amd inject this compressed air into the seawater conduits to increase flow with no addedd energy
3) Add a Solar booster to the gas just befire the turbine in the closed Rankine cycle to increase the energy output.
4) All components with exception of the PSC's are housed in factory prefabricated 40 foot shipping containers. Turbines, heat exchangers, solar collectors, wind turbines are then cost effectively produced and replicated. Modules can be combined to make whatever size plant is required.

This is described in a powerpoint on my website http://www.cotherma.com/PowerShrink_SolAirOTEC_Introduction_Mar_2008.pps

I will be writing to the founders of OTEC, Dr. Cohen, Dr. Krock, Dr. Panchal, Tom Plocek and others to get their comments on how to get the OTEC ball rolling again.
My patents are published on the USPTO website and anyone is welcome to comment. My view on patents are that they are excellent for patent attorneys to feed their family. I use my patents as "Weapons of Mass Construction" to get the word out of an idea that just may change the world for good.

Again, Mr Barry and Dr. Cohen thank you for keeping the OTEC torch lit.
Alejandro Herrera
Alejandro Herrera
November 21, 2008
Dr Cohen
Your work is exiting and promising. I did not know about the project until now. As I see that one of the engineering challenges is the mooring of the huge cold water riser tubes, and making it survive the huge stresses it will be subjected to, our company may be of help. We are a Norwegian company specialized in mooring. We will possibly be cooperating in the mooring of the first giant ocean current turbines for which specialized dynamic simulation for the mooring and the turbine structure has been developed. If you are interested please contact us at alex@haugaqua.cl
Rob Hart
Rob Hart
October 14, 2008
How fascinating to read posts from Dr.'s Takahashi and Cohen on this message board! I've been reading both of your published works on OTEC for awhile now. It's neat to see you contributing to online discussions as well as publishing full blown academic research. I'm curious what you all would believe the U.S. Federal Government's role in OTEC development should be. Do tax incentives like REPI go far enough in promoting OTEC? Should we increase existing incentives or establish a new one altogether that's OTEC specific? Given that no utility company (or private investor) can even make use of a tax credit until they're actually generating power off OTEC, it would seem to me that we need something a little bit more reaching at the federal level that guarantees private interest in OTEC. What do you all think?
Catherine Kaiser
Catherine Kaiser
July 16, 2008
Time to think outside of the box, gentlemen. One, how to capture the natural energy of the ocean currents and undercurrents? Nature has always provided living creatures with what they need to survive. Throughout the expand of the oceans, the ocean currents and undercurrents run on a steady pattern. This energy is a constant and the force of this energy generates much needed oxygen for our marine life. The question now is how to navigate and execute a feasible and practical plan on how to harvest this energy. First, much like electrical grids these grids would need to be placed throughout the the ocean floor, and much like solar panels these grids would tap not only the electrical and solar energy, but would have the sensitive computer chips to predict earthquakes, hurricanes, tsunamis, and global warming within the ocean with a communication device that would not only give countries a heads up but an advance warning that would save millions of lifes. For instance, like cell towers for your cell phone, the signal would be polarized, using the earth's natural magnetic field to constantly maintain the correct amount of power generated and the direction it is needed to flow through. (Consider a compass and how it works). The emissions and footprints that it would expell would be oxygen that it pulls from the water and it is excreted back into the ocean water at a level that is consistant with maintaining marine life. These new "computer" grids would generate enough electricity and power to sustain the human population on this earth for the next 2 billion years, in every country across the world. As to maintenance a gps locator chip would be in each grid to monitor it's location. Any volcanic/vaults along the ocean floor could be monitored at all times and the grids could be electronically and remotely moved to a different location or direction. Nasa and governments across the world would come together to implement policies and procedures on it's operation.
Robert Cohen
Robert Cohen
July 16, 2008
There is now an Ocean Thermal Energy group on the PickensPlan Web site.

I encourage you to have a look at it, and to participate in it, at URL http://push.pickensplan.com/group/oceanthermalenergy
You may have to sign up when you arrive at that Web site.
Thomas Bjelkeman-Pettersson
Thomas Bjelkeman-Pettersson
July 8, 2008
C. Barry said: "Again, with ammonia as the example, ammonia attacks copper bearing alloys, but only copper alloys resist marine fouling, and only a small amount of fouling is enough to drastically cut efficiency. Systems using ammonia have to have sophisticated waterside cleaning systems. "

Can not the heat exchanger be non-copper alloy on the inside of the Closed Cycle OTEC (the part which contains the ammonia working fluid) and a copper alloy on the seawater exposed side? Or am I missing something?

Thomas Bjelkeman-Pettersson
Thomas Bjelkeman-Pettersson
July 8, 2008
C. Barry said: "Again, with ammonia as the example, ammonia attacks copper bearing alloys, but only copper alloys resist marine fouling, and only a small amount of fouling is enough to drastically cut efficiency. Systems using ammonia have to have sophisticated waterside cleaning systems. "

Can not the heat exchanger be non-copper alloy on the inside of the Closed Cycle OTEC (the part which contains the ammonia working fluid) and a copper alloy on the seawater exposes side? Or am I missing something?
Robert Cohen
Robert Cohen
July 5, 2008
A useful overview. Here are some constructive comments, based upon my experience since becoming, in 1973, the program manager who designed and conducted the original U.S. ocean thermal energy R&D program. At that time, OTEC R&D had equal status with R&D on the other five major renewable energy sources: wind, photovoltaics, biofuel, heating/cooling of buildings, and solar thermal.

Re assigning credit and blame, the U.S. renewable energy R&D began at NSF/RANN around 1972, under President Nixon's Operation Energy Independence. Those RE R&D programs thrived and grew during the Nixon, Ford, and Carter Administrations. However, the Reagan Administration tried to cut all of the RE budgets, singling out OTEC R&D for zero funding, just as DOE was about realize a 40MWe OTEC plant in Hawaii. DOE ocean energy waned to zero in 1995 during the Clinton Administration.

Re theoretical and net efficiency, they ought to be maximized. But the economic bottom line is the cost of the baseload electricity per kWh. That cost is the plant's amortized capital cost plus the O&M cost, there being zero fuel cost. The range of capital costs of a commercial OTEC plant depends upon its maturity and size (in view of economies of scale). One current estimate for the first commercial plant, say 75MWe, is $8,000 per kWe. After some experience, subsequent plants up to about 500 MWe in size might cost as little as half that amount per kWe. That first plant would generate electricity costing about 15¢/kWh.

OTEC can provide renewable, baseload power, which can offset considerable oil and gas use and thereby mitigate global warming. Insofar as CO2 emissions, OTEC plants must be operated so as to avoid liberating CO2 to the atmosphere. On the other hand, there is a promising possibility that the plants could, in the course of circulating "a river of seawater", en passant remove CO2 from the atmosphere and sequester it below the thermocline.
Robert Cohen
Robert Cohen
July 5, 2008
If I am permitted to add some concluding sentences to what I just posted, they are as follows:

Much would depend upon the dwell-time of the effluent seawater below the thermocline, and pH considerations. But the incremental cost of achieving such avoidance and sequestering would have to be considered and internalized into the plant economics. Trying to use upwelled nutrients for mariculture would complicate the CO2 picture.

There are two important factors in avoiding CO2 emissions: 1) design of the OTEC power cycle and 2) the circulation of the "not-so-cold" seawater effluent. The "closed" power cycle would probably qualify, but if the "open" power cycle is used, care must be taken to avoid liberating CO2 to the atmosphere. During the 70s, the fate of the CO2 dissolved in the cold water was not an issue. Instead, the goal was to avoid perturbing the thermal environment of the plant. Hydrodynamic modeling studies conducted at MIT and Cornell led, e.g., to one way of dealing with the seawater effluents; namely, to mix them, then discharge the mixture at a depth matching its resulting temperature. Nowadays, avoiding liberation of CO2 must also be a goal in modeling how to dispose of these seawater effluents.
Sandra Betts
Sandra Betts
July 4, 2008
Johnathon Cole
here in Australia we send electric power (from hydro source) from Tasmania to Victoria, via under sea cable, across Bass Strait (Its maximum width is 150 miles (240 km), its depth is 180–240 feet (50–70 m)). A monopolar was installed although we would have preferred bipolar cables for energy efficiency and marine environment protection (cost being the deciding factor for the government)........and Bass Strait is renowned for its storms
Jonathan Cole
Jonathan Cole
July 4, 2008
Sandra,

I would be interested in getting more info about that underwater power cable technology. As to the application for OTEC, the problem is not whether electrical energy can be transmitted through underwater cables, but rather, how the cables are terminated. When the cable ends are on land in a fixed and stable installation that is much different than connecting to a floating OTEC plant that can be buffeted by huge wave and storms. The stretching, twisting and oscillating forces on such a cable termination could be enormous and very difficult to guarantee. Perhaps the cable end could be attached to a mooring and set free in such extreme conditions. In any case it would be a major engineering issue.
Patrick Takahashi
Patrick Takahashi
July 4, 2008
Nice to see some growing interest in OTEC. I helped draft that original OTEC bill when working for U.S. Senator Spark Matsunaga in 1979, where we blithely predicted 10,000 MW of this power by 1999. Okay, we were off by 10,000 MW, but Lockheed Martin has returned to the scene of their Mini-OTEC success, and hopes are high for their continuing invovlement to complement the efforts of Hans Krock, Bob Nicholson and Saga University. Here I go again, but I predict a 100 MW OTEC plantship providing electricity and freshwater to Honolulu before 2020, and, maybe by 2015.

By the way, Chapter 4 of SIMPLE SOLUTIONS for Planet Earth (http://SimpleSolutionsBook1) is entitled The Blue Revolution, and provides the full range of details on how this total marine product system can be developed. And, of course, your readership must be aware of Doug Carlson's blog at http://HawaiiEnergyOptions.blogspot.com, dedicated to OTEC.
Jay Rosenberg
Jay Rosenberg
July 3, 2008
9.2% "aint" bad, when you realize that Concentrated Solar Power (CSP) may net you 20%.. But the sun only shines less than half the day, and particulates, rain, clouds etc., befuddle your net power output. And, most likely you need expensive thermal storage, to load match, power shift, and get 24 x 7 energy. So after normalizing matters, 9.2% OTEC may equal 20% CSP. OTEC housekeeping is not an insurmountable problem.

My company has a very high efficiency, low temperature differential "power block" for concentrated CSP. Its applicable to geothermal, OTEC, OWEC (Ocean Wave Energy Conversion), and automobiles/ transportation (fuel efficiency, means thermal efficiency, is the other side of the "cracking energy" coin.). However, it is hard to get access to serious Enterprise, Endeavors and players in this domain. Suggestions? Sannerproejcts Inc, JRIAM1945@aol.com

Without punning, once you get into this pool, you will see the other harvestable potentials, which can augment the business models. Its not just raw energy output, often, it's the application of that power, and resultant cash positive cash flows. An oceanic base, has inherent opportunity-stock, ie, water which can be desalinated, mineral content, bio-mass, and as enumerated several energy-stock forms be they, wave, wind, current, tides, etc. that my proximity should be and could be integrated.
Wesley Sugai
Wesley Sugai
July 2, 2008
Aloha Peter, you are correct. I live a few miles from NELHA and know many of the commercial tenants' employees. Hopefully, we can expand the OTEC plant and provide more power to our community here. The cold water drawn up is used not only for power but to help many other industries that include "farms and hatcheries" to biopharmaceuticals and even boutique drinking water that the Japanese enjoy.
http://www.nelha.org/tenants/commercial.html
Jonathan Cole
Jonathan Cole
July 2, 2008
I have been a follower of OTEC for many years. Having particularly identified parasitic pipe friction losses as the central issue, I realized that the floating straight pipe design from Sea Solar Power made a lot of sense. Shortest pipe, least friction.

However as you noted in your article getting the energy to shore is as yet not solved. Solar Sea Power's idea of underwater high power/voltage cables seemed a bit of a stretch for me, having once been on board a cruiseship about 90 miles from a hurricane.

However, there are ocean islands of relative calm, known as anti-cyclones where such installations could under their own power, slowly dial in the ideal marine environment. These are too far from land to be candidates for underwater cables. However, as you pointed out, the manufacture at sea of some kind of fuel bearing substance that could be shipped is a good direction for exploration.

Another potential use would be to utilize the energy for the processing of industrial feedstocks. For example there are billions of tons of mixed plastics floating in the North Pacific gyre, that are wreaking havoc on the marine ecosystem. Perhaps OTEC could be used as an energy source to return these increasingly valuable materials to pure industrial feedstocks. There are a few companies developing the technology to make this possible.
http://globalresourcecorp.com/index.asp

Some versions of OTEC technology also produce millions of gallons of fresh water as a byproduct. The issue of how to utilize this resource without permanently altering the local sea temperature conditions which would dissipate the temperature differential is an important consideration.
Re-inject the deep water?

Solar thermal collectors on the surface of the installation may be practically employed to increase the temperature differential or to power the movement of the floating plant. One kW per square meter can add up on a large floating installation.
michael macrumpton
michael macrumpton
July 2, 2008
I wonder if combining the wave powered pumps with the stirling or turbine technology would make sense. One of the big energy drains in an OTEC system has to be moving the cold water to the surface. Using wave or wind powered pumps to move the water would take that strain off the thermal system. Also pumping water is quite simple and efficient with both wave and wind power.
Doni Mae
Doni Mae
July 2, 2008
The potential of OTEC seems excellent, but I can't help but recall many comments about the toxic substances that civilization has dumped into the oceans, of which mercury is the most famous. I hope the designers of OTEC will consider this. Toxic elements are often valuable when used appropriately, so it might be worthwhile to recycle them.
Richard Moore
Richard Moore
July 2, 2008
Has there been any research on ocean current energies? We could have current farms much like wind farms on land. I have worked in the offshore oil and gas industry, also in the dredging industry . I know that ther are ocean currents close to shore and stronger sustained currents farther out. We have the tech. to lay and bury cables on the ocean floor so lets farm the oceans energy!!
Peter Hain
Peter Hain
July 1, 2008
Credit is also due to Dr. John Craven and Dr. Patrick Takahashi. Sea Solar Power, Dr. Luis Vega and Dr. Hans Krock have kept the torch alight all these years. The first net power generating plant was operated in Hawaii at NELH in 1979. The US could take the lead in developing large scale OTEC plants and could employ and retrain shipyard and auto workers to assemble them. Lockheed-Martin is developing commercial scale technology. The US can either sell these plants to the world or let the world, (Japan, Korea, Taiwan) "eat our lunch". This is not a difficult choice. OTEC needs to get its rightful share of upcoming federal renewable energy R&D funding. OTEC can indeed save the world if employed and deployed in a Manhatten/Apollo project committment.

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Chris Barry

Chris Barry

Christopher D. Barry, P.E. is a naval architect and co-chair of the Society of Naval Architects and Marine Engineers ad hoc panel on ocean renewable energy. He has worked in design agencies, shipyards and manufacturers in the marine industry...
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