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October 30, 2008

Turning Waste Olive Stones Into Bioethanol

Granada, Spain [RenewableEnergyWorld]

Olive stones (pits) could be the newest ethanol feedstock used in Spain and could give the olive processing industry an opportunity to turn the 4 million tons of olive stones it generates every year into a valuable asset.

"This research raises the possibility of using of olive stones, which would otherwise be wasted, in producing energy. In this way we can make use of the whole food crop."

--Sebastián Sánchez, Researcher, University of Jaén

Researchers from the Universities of Jaén and Granada have now shown how this can be achieved in a study published in the latest edition of the Society of Chemical Industry's (SCI) Journal of Chemical Technology & Biotechnology.

The olive stone, removed when processing raw olives for use as olive oil and table olives, makes up around a quarter of the total fruit. It is rich in polysaccharides (cellulose and hemicellulose) that can be broken down into sugar and then fermented to produce ethanol.

The team pre-treated olive stones using high-pressure hot water then added enzymes that degrade plant matter and generate sugars. The hydrolysate obtained from this process was then fermented with yeasts to produce ethanol. Yields of 5.7 killograms (kg) of ethanol per 100kg of olive stones have been reached.

"The low cost of transporting and transforming olives stones make them attractive for biofuels," said Sebastián Sánchez, a researcher in the Department of Chemical, Environmental and Materials Engineering at the University of Jaén.

 

Reader Comments (7)
 
No image available
October 31, 2008
I wonder if there would be a net benefit from using the 'stones' like wood pellets and burning them in a boiler directly...
Comment 1 of 7
No image available
October 31, 2008
As per defination of Olive stone, it is an excellent source of raw materials for ethanol production and lignin as by-product. Olive stone has some advantage on collection, storage point of view compared to other agricultural residues such as straw, cornstover, switchgrass, etc.
Comment 2 of 7
No image available
October 31, 2008
My wondering based on John's above, is whether there is much need for heat in Spain, and if so, if rocket-stove technology could be harnessed in burning those stones.

This is a technology that needs to migrate to Palestine as well.

I know of someone around here using rocket-stove technology to heat cob benches before venting exhaust.

Harvesting presently wasted heat is a topic that interests me.

Extending the growing season and cooking are other possible uses for waste heat.

The fermenting process itself generates heat. If you properly mix your nitrogen and carbon sources, you can get a good 150-160, which effectively
pasteurizes food for fragile populations. I know a guy who heated all the water his 5-person family used for 18 months this way.

Coppice wood from pruning is another source.

Seed-coat digesting enzymes are also present in mash from the fermenting process, and mash forms a safe pre-emergent herbicide for that reason, although it's higher use is often as animal feed.

Animals fed with mash are so healthy that the Bureau of Alcohol, Tobacco, and Firearms often visits the farmers whose animals win prizes at county fairs, a reason some of the best animals may not show up at county fairs any more.

We really need to get going on sensibly using surplus as resources that were formerly thought of as waste.

We can rehabilitate our image around the world by ceasing to throttle back production to elevate prices.

The better choice would to to share left-overs and how-to's and let prices be accessible to wider markets. The current deflation is sort of doing that. Places like MIT that share information so as to find the most innovative minds around the world have long benefited from sharing.

In some respects, it is fortunate that bad renewable products haven't so far been subsidized too much. The present oil-price manipulations are going to cut some knees off, but not as many.
Comment 3 of 7
No image available
October 31, 2008
Another approach to solve the problem of the olive stones is to ferment them anaerobically to make methane gas. This is due to the paste form of the pits. By this way, the energy used in the generation of high-pressure hot water can be saved.
Since the yield of the ethanol produced by the process mentioned above is relatively low, can it be justified economically ?
Comment 4 of 7
No image available
October 31, 2008
The HHV (higher heating value) of ethanol is 29.8MJ/Kg and I have found an article which quotes the HHV (higher heating value) of the stones as 17.7MJ/kg, (sounds about right) and on this basis the energy in 5.7Kg of ethanol represents about 9.6% of the energy in the original 100Kg of stones, not particularly good return but it gets worse. My guess is that the ethanol will end up as petrol substitute, in a car with a T2W (tank to wheel) efficiency of about 25% (combined town/highway cycle) so the final energy yield is about 2.5% of the original feedstock.
Alternatively, burn them any other way to produce electricity, even straight burning in a biomass power station should convert at least 35% to electricity. Now use this to run BEV's (battery electric vehicles) operating at 80% T2W efficiency and the combined efficiency is 28%, over eleven times better than the ethanol route!!
In general I would say that bioethanol production is a poor use use biomass energy resources if it ends up in the fuel tanks of cars.
Comment 5 of 7
No image available
November 1, 2008
You need to digest 100 kg of olive stones with enzymes in order to obtain sugars. Then you need yeasts to ferment the sugars and obtain 5.7 kg of ethanol.
What is the final cost of such an ethanol?
To obtain a cheap ethanol by that way you surely need new robust enzymes and new robust fermentors.
I never heard current enzymes and current fermentors are cheap.
I heard of people overcoming chemical production of ethanol by producing it biotechnologically, spending ten dollars of enzymes to obtain one dollar of ethanol. An academic exercise. Having money to burn, it is easy to do everything, even fabricate natural diamonds.
Comment 6 of 7
No image available
November 4, 2008
Ms Saunders mentioned above quite corrently:

"Animals fed with mash are so healthy that the Bureau of Alcohol, Tobacco, and Firearms often visits the farmers whose animals win prizes at county fairs, a reason some of the best animals may not show up at county fairs any more."

Perhaps if we fed our animals highly nutrient dense mash around the globe before slotter, we would have a lower incidense of heart attacks and strokes around the world; especially in the US. "You are what you eat, not what you don't eat." Indisputable logic.

Oh well,...we're just complacent Americans, we don't care about anything but our couches and our T.V's. probably because our food stocks provide so little nutrient density unless we pay ten times more for our meals at health food stores; or spend half a life time studying nutrition. Here's to long shelf live and dead food! Yeeeaaah!

Where are my potatoe chips?!
Comment 7 of 7
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