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Texas Biodiesel Ban Delayed

By Stephen Lacey, Staff Writer
January 8, 2007   |   8 Comments
Texas Commission on Environmental Quality seeks more evidence in debate over nitrogen oxide emission levels.

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"We are looking at this potential decision very seriously. To be very blunt about it, if Texas follows through then we will immediately move toward Louisiana and Mississippi and we won't build any more facilities in Texas."

-- Brent Kartchner, Co-owner and Director of GeoGreen Fuels
8 Reader Comments
Comment
1 of 8
January 10, 2007
Regarding the first writers comments:
The EPA's own research shows the airborne exhaust emissions from heavy-duty diesel engines burning bio-diesel, made from agricultural and other solid waste, are dramatically reduced. Carbon monoxide and particulate matter emissions are both reduced 12% using B20 (20% bio/petro mixture) and 48% using B100 (pure) bio-diesel. Reductions of hydrocarbons are 20% and 77% respectively.
The only thing keeping bio-diesel from being a perfect fuel is that nitrogen oxide emissions (Nox) slightly increase to 3% and 10% respectively. An EPA/NREL report states there is "no increase in ozone levels" from burning bio-diesel.
Jim Duncan
Comment
2 of 8
January 10, 2007
Simply the fact that the TCEQ is trying to ban bio-diesel in the same state where it is fast-tracking construction of 12 coal-fired electric power plants displays the bias and hyprocity of that agency. Their opinions deserve to be be considered in that light.
Jim Duncan
Comment
3 of 8
January 10, 2007
...hydrocarbon emissions are 35% higher on a life cycle assessment.

Emissions are 35% higher than what?
Comment
4 of 8
January 10, 2007
In addition to removing 15 acres worth of soybean oil off the futures food market to run your average American car annually, biodiesel has pollution concerns as well. B-100 releases 10% more NOx than diesel at the exhaust and hydrocarbon emissions are 35% higher on a life cycle assessment. Overall, it is cleaner than regular diesel, but people who replace gasoline cars with cars that burn biodiesel are creating a lot of unnecessary air pollution.
Comment
5 of 8
January 11, 2007
NOx emission directly relates to combustion temperature. Combustion temp is easily controllable to obtain low NOx. NOx is reduced by 50% for each 150 deg F reduction in combustion temp. 2.0#NOx/MBTU at 3400F, 1.0 at 3250, 0.5 at 3100 deg F, 0.25 at 2950 deg F, etc. rule of thumb all else equal.
Why did the EPA test a limited number of high temp engines that emit high NOx? Why did the EPA not test a representative number of well tuned engines?
Big Petro is appeased, Authorities are puzzled, the public is duped once again by accurate but misleading EPA data.
Check and Find EPA listing better mileage in town than on the highway for any one specific Electric Vehicle. Granny knows better. Granny knows the faster you walk the more distance covered & the sooner you arrive. Commuting in heavy traffic or stopped at a traffic light is near zero mpg unless coasting. EPA data may be accurate but extremely misleading.
Comment
6 of 8
January 11, 2007
Nitrous Oxide in biodiesel specially made thru esterification, could cetainly hazadous to the atmospher, more so, if it is only used as an additive to petro-diesel.

Esterification:
In organic chemistry, transesterification is the process of exchanging the alkoxy group of an ester compound by another alcohol. These reactions are often catalyzed by the addition of an acid or base.

Redox (Redirected from Oxidation)
Redox reactions include all chemical processes in which atoms have their oxidation number (oxidation state) changed.

Combustion of hydrocarbons, e.g. in an internal combustion engine, produces water, carbon dioxide, some partially oxidized forms such as carbon monoxide and heat energy. Complete oxidation of materials containing carbon produces carbon dioxide.

visit: http://www.enkocogreengold.zoomshare.com
Comment
7 of 8
February 12, 2009
Seems like folks are mixing terms here, nitrous oxide, nitrogen oxide, maybe I even read nitric oxide...

Weren't catalytic converters implemented on gasoline cars to reduce these types of nitrogen compound emissions in mid-70s? weren't exhaust gas recirculation valves implemented as well to cool the combustion chambers as Mr. Clift pointed out. Again, the EPA tested on one engine with no "fuel-specific" tuning and decides a ban is appropriate?!?

Mr. Diores says the nitrous oxide(?) is in biodiesel produced through esterification, wouldn't the nitrogen compound provide oxygen to the combustion process and catalysts could modify the exhaust as gasoline cars are now?

How would hydrogen/oxygen enrichment affect these numbers using B100?
Comment
8 of 8
February 12, 2009
@Mr. Finley: Food isn't required to make biodiesel unless you are eating palm, rapeseed and/or jatropha.

Would please cite the source for the empirical data to support this statement:

"B-100 releases 10% more NOx than diesel at the exhaust and hydrocarbon emissions are 35% higher on a life cycle assessment. Overall, it is cleaner than regular diesel, but people who replace gasoline cars with cars that burn biodiesel are creating a lot of unnecessary air pollution."
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